کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
63281 47679 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Enhanced cooperative, catalytic behavior of organic functional groups by immobilization
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Enhanced cooperative, catalytic behavior of organic functional groups by immobilization
چکیده انگلیسی

The addition of thiol to the sulfonic acid-catalyzed condensation of phenol and acetone to give bisphenol A is investigated using homogeneous and SBA-15-immobilized sulfonic acids. Inclusion of thiols into the reaction media of either type of sulfonic acid catalyst accelerates the rate of reaction and shifts the regioselectivity to favor the formation of the p  ,p′p′-bisphenol isomer (bisphenol A) over the unwanted o  ,p′p′-bisphenol isomer. By immobilizing the thiol on the same solid as the sulfonic acid, reaction rates and regioselectivities are enhanced even further from those obtained from using mixtures of these two functional groups (when they are both homogeneous, or a combination of homogeneous and heterogeneous). A mechanism is proposed to explain the reactivity and involves cooperative interactions via the proximity of the immobilized sulfonic acid and the immobilized thiol. This enhanced reactivity can only be achieved by immobilizing the two functional groups on a solid.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 239, Issue 2, 25 April 2006, Pages 299–306
نویسندگان
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