Hydrogen permeation through palladium membranes and inhibition by carbon monoxide, carbon dioxide, and steam

• Systematic inhibition experiments with CO, CO2, and H2O at 22 bar and 350–450 °C.
• CO and H2O lead to inhibition of H2 permeation.
• CO2 does not lead to inhibition, except via in situ produced CO.
• Constriction resistance model derived for H permeation under inhibition.
• Membrane thickness strongly determines its susceptibility to inhibition.

Palladium membranes are being developed for the separation of hydrogen from syngas in industrial applications. However, syngas constituents carbon monoxide, carbon dioxide, and steam are known to adsorb at the membrane surface and inhibit the permeation of hydrogen. The current study combines an experimental study and modelling approach in order to investigate and quantify the inhibition effects. Experiments have been performed with a 2.8 μm thick palladium membrane (surface area 174cm2) on a tubular alumina support, including systematic variation of the concentrations of carbon monoxide, carbon dioxide, and steam at 22 bar total pressure and 350–450 °C. Carbon monoxide and steam inhibit hydrogen permeation. No significant effect has been found for carbon dioxide, except indirectly by carbon monoxide produced in situ from carbon dioxide. A constriction resistance model has been derived, explicitly relating the decrease in surface coverage by adsorbed hydrogen to the ensuing decrease in transmembrane flux. Very high surface coverages by inhibiting species θi>0.995θi>0.995 are predicted. The results highlight that inhibition effects are greatly reduced at high hydrogen partial pressures due to competitive adsorption. Due to the lateral diffusion of permeating hydrogen atoms in the metallic membrane, the thickness of the palladium membrane strongly determines the extent to which surface coverage by non-hydrogen species causes a decrease in hydrogen transmembrane flux. Depending on the operating conditions, membranes are predicted to have an optimal minimum thickness below which an increased intrinsic permeance is offset by an increased impact of inhibition.

Figure optionsDownload high-quality image (181 K)Download as PowerPoint slide