کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
632974 1456015 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation, characterization, and properties of poly(styrene-b-sulfonated isoprene)s membranes for proton exchange membrane fuel cells (PEMFCs)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Preparation, characterization, and properties of poly(styrene-b-sulfonated isoprene)s membranes for proton exchange membrane fuel cells (PEMFCs)
چکیده انگلیسی


• Poly(styrene-b-sulfonated isoprene) membranes were prepared.
• The membranes produce proton conductivity values up to 10−1 S/cm above 60 °C.
• The membranes benefit from 50% lower methanol permeability than that of Nafion-117.
• As the hydrophilic block length is increased, the proton conductivity also increased.

A series of poly(styrene-b-isoprene) block copolymers (PSI) were synthesized by sequential anionic polymerization of styrene and isoprene. Poly(styrene-b-sulfonated isoprene) block copolymers (PSsI) were prepared via reacting the double bonds of the isoprene block with 1,4-dioxane/sulfur trioxide. The spherical-shaped ionic clusters within the PSsI membranes produce a comparable proton conductivity (10−1 S/cm above 60 °C) but benefits from approximately 50% lower methanol permeability than that of Nafion-117. Properties, such as proton conductivity and water content values, of PSsI membranes correlate highly to the content of the sulfonated isoprene block in PSsI samples even in the cases of similar IEC. As the hydrophilic block length is increased, the water content and proton conductivity also increased.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 484, 15 June 2015, Pages 146–153
نویسندگان
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