کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
633282 1456025 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The functional separator coated with core–shell structured silica–poly(methyl methacrylate) sub-microspheres for lithium-ion batteries
ترجمه فارسی عنوان
جداسازی عملکردی با ذرات زیر میکروسکپرس سیلیکا پلی (متیل متاکریلات) ساخته شده با هسته پلاستیکی برای باتری های لیتیوم یون
کلمات کلیدی
ساختار هسته پوسته، جداکننده سرامیکی پوشش داده شده، باتری لیتیوم یون، پلی (متیل متاکریلات)، توانایی نگهداری الکترولیت
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی


• Core–shell structured SiO2–poly(methyl methacrylate) sub-microspheres are prepared.
• A functional ceramic-coated separator coated by the sub-microspheres is developed.
• The separator exhibits good thermostability and electrolyte retention ability.
• The separator multi-functionality provides cells with greater safety performance.

To improve the safety of lithium-ion batteries (LIBs), a functional ceramic-coated separator (FCC separator) is developed by coating core–shell structured silica–poly(methyl methacrylate) (SiO2–PMMA) sub-microspheres on one side of a conventional porous polyethylene (PE) separator. The FCC separator possesses multi-functional properties of better separator thermostability and higher electrolyte stability by combining the advantages of both the ceramic-coated separator and the gel polymer electrolyte (GPE). The heat-resistant SiO2 core particles effectively protect the FCC separator from thermal shrinkage. Meanwhile, the PMMA shells form a gel after swelling and activation by the liquid electrolyte, which endows the FCC separator with the functional properties of the GPE to stabilize the electrolyte. As a result, the FCC separator shows considerable wettability for the liquid electrolyte and outstanding electrolyte retention ability at elevated temperature. Moreover, the FCC separator with the coating layer improves the safety performance of cells by preventing cells from experiencing internal short circuits at high temperature. Meanwhile, the cells assembled with such separators demonstrate superior cycle performance and C-rate capability. Therefore, the FCC separator provides LIBs with greater security and better electrochemical performance.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 474, 15 January 2015, Pages 148–155
نویسندگان
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