کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
633283 1456025 2015 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Constructing CO2 transport passageways in Matrimid® membranes using nanohydrogels for efficient carbon capture
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Constructing CO2 transport passageways in Matrimid® membranes using nanohydrogels for efficient carbon capture
چکیده انگلیسی


• Composite membranes comprising nanohydrogels and Matrimid® were prepared.
• Nanohydrogels increase water content and water retention capacity of membranes.
• Interconnected CO2 transport passageways were constructed within membranes.
• Membrane performance surpassed or was close to the 2008 Robeson upper bound line.

Composite membranes were fabricated by incorporating poly(N-isopropylacrylamide) nanohydrogels (NHs) into Matrimid® 5218 matrix to improve the separation performance for CO2/CH4 and CO2/N2 mixtures. The membranes were characterized by a fourier transform infrared spectrometer (FT-IR), scanning electron microscopy (SEM), tensile test, dynamic mechanical analysis (DMA), X-ray diffraction (XRD), positron annihilation lifetime spectroscopy (PALS), the static contact angle and water content measurement. The incorporation of nanohydrogels increased the fractional free volume of the composite membranes, water uptake and water retention capacity. The composite membranes displayed better performance than the pure Matrimid® membrane. The nanohydrogels homogeneously embedded in the Matrimid® matrix acted as water reservoirs to not only provide more water for dissolving CO2, but also construct interconnected CO2 transport passageways. The as-prepared Matrimid®/NHs-20 composite membrane showed CO2/CH4 and CO2/N2 selectivities of 61 and 52 with a CO2 permeability of 278 Barrer, surpassing or being close to the 2008 Robeson upper bound lines.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 474, 15 January 2015, Pages 156–166
نویسندگان
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