کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
634099 1456056 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of novel cross-linked polybenzimidazole membranes for high temperature proton exchange membrane fuel cells
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Synthesis of novel cross-linked polybenzimidazole membranes for high temperature proton exchange membrane fuel cells
چکیده انگلیسی


• Two new cross-linked PBI membranes have been synthesized.
• The oxidative stability of cross-linked PBI under the Fenton's test was improved.
• The mechanical and thermal properties were improved by the cross-linking method.
• This method did not sacrifice the proton conductivity of the membranes.

Polybenzimidazole (PBI) copolymer containing hydroxyl functional groups was synthesized in this study. Two series of cross-linked PBI membranes have been prepared based on the copolymer with two different crosslinkers reacted with the hydroxyl groups on the PBI main chain. The resultant membranes were investigated in terms of oxidative stability, thermal properties, mechanical properties, and proton conductivity. The mechanical and thermal properties were enhanced in the cross-linked membranes compared to the non-cross-linked membrane. In addition, the thermal degradation temperature of the membranes increased with increasing degree of cross-linking. The Fenton's test was used as the reference of the oxidative stability of the membranes. It was found that cross-linking led to a significant improvement in oxidative stability of the membranes. The proton conductivity of phosphoric acid doped cross-linked PBI membranes could reach 8×10−3 Scm−1 at 160 °C.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 443, 15 September 2013, Pages 138–143
نویسندگان
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