کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6341021 | 1620386 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Seasonal and diurnal variations of particulate organosulfates in urban Shanghai, China
ترجمه فارسی عنوان
تغییرات فصلی و روزانه ارگانواسولفات ذرات در شهر شانگهای چین
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کلمات کلیدی
اورانوسولفاتها، اسپری های آلی متوسط، شانگهای، ذرات جامد،
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
علم هواشناسی
چکیده انگلیسی
PM2.5 samples have been collected in urban Shanghai, China, during April (spring), July (summer), October (autumn) 2012, and January (winter) 2013, respectively. Seventeen organosulfates (OSs) derived from isoprene, α-/β-pinene, and presumably aromatic precursors were quantified using a high-performance liquid chromatogram coupled to a triple quadrupole mass spectrometer. During our sampling days, the total concentration of detected OSs ranged between 0.0209 and 60.8 ng mâ3 (sodium octyl sulfate and benzyl sulfate as standards). The seasonal average concentration of OSs was the highest (26.2 ng mâ3) in summer 2012 and the lowest (0.510 ng mâ3) in spring 2012, accounting for 0.471â° and 0.00965â° of the corresponding PM2.5 mass, respectively. Isoprene- and α-/β-pinene-derived OSs showed a clear seasonal fluctuation with a peak in summer, whereas OS derived from aromatic precursors was less variable in most seasons. The share of aromatic OS in the total measured OSs was the highest (63.5%) in winter 2013 and the lowest (2.94%) in summer 2012, suggesting that aromatic OS could serve as an important component of the OS species in urban Shanghai. In addition, a number of OSs demonstrated distinct diurnal profiles, reflecting diverse formation mechanisms with multiple atmospheric oxidants in an urbanized area like Shanghai.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Atmospheric Environment - Volume 85, March 2014, Pages 152-160
Journal: Atmospheric Environment - Volume 85, March 2014, Pages 152-160
نویسندگان
Ye Ma, Xinkai Xu, Weihua Song, Fuhai Geng, Lin Wang,