Observation of ions and particles near busy roads using a neutral cluster and air ion spectrometer (NAIS)

- Measured cluster ion and charged particle concentrations near high traffic density freeways.
- Determined spatial distribution of concentrations.
- Motor vehicles produced both cluster ions and charged particles.
- Cluster ions quickly attached to particles and rapidly decreased near the kerb.
- Elevated charged particle concentrations extended up to 400 m downwind of freeway.

Motor vehicles emit large quantities of ions in the form of both charged particles and molecular cluster ions. While, the health effects of inhalation of charged particles is largely unexplored, the concentrations near busy roads and the distance to which these particles and ions are carried have important implications for the exposure of the large percentage of the population that lives close to such roadways. We measured ion concentrations using a neutral cluster and air ion spectrometer (NAIS) near seven busy roads carrying on the average approximately 7000 vehicles h−1 including about 15% heavy duty diesel vehicles. In this study, charged particle concentrations were measured as a function of downwind distance from the road for the first time. We show that, at a moderate wind speed of 2.0 m s−1, mean charged particle concentrations at the kerb were of the order of 2 × 104 cm−3 and, more importantly, decreased as d−0.6 where d is the distance from the road. While cluster ions were rapidly depleted by attachment to particles and were not carried to more than about 20 m from the road, elevated concentrations of charged particle were detected up to at least 400 m from the road. Most of the charge on the downwind side was carried on the larger particles, with no excess charge on particles smaller than about 10 nm. At 30 nm, particles carried more than double the charge they would normally carry in equilibrium. There are very few measurements of ions near road traffic and this is the first study of the spatial dispersion of charged particles from a road.

103