Dense film polyimide membranes for aggressive sour gas feed separations

Dense film membranes of the copolyimide 6FDA-DAM:DABA (3:2) are studied for simultaneous removal of CO2 and H2S from sour natural gas streams. Pure and mixed gas permeation as well as pure gas sorption data are reported at 35 °C and pressures up to 62 bar. The H2S partial pressures used are representative of highly aggressive field operations. Penetrant-induced plasticization effects are evident at feed pressures below 1 bar in pure H2S feeds; sub-Tg thermal annealing is used to effectively mitigate this effect, and these annealed films are used throughout the study. Surprisingly, H2S/CH4 selectivity nearly doubles for mixed gas testing in comparison to the pure component ideal selectivity values and approaches the level of a state-of-the-art glassy polymer, cellulose acetate (CA), at H2S partial pressures above 2 bar. Furthermore, permeation experiments using a 9.95% H2S, 19.9% CO2, 70.15% CH4 mixture at low feed pressures give CO2/CH4 selectivity of up to 49—over 30% greater than the pure component selectivity for 6FDA-DAM:DABA (3:2). The overall sour gas separation performance of this polyimide is comparable to high-performance rubbery polymer membranes, which have been reported for only moderate H2S partial pressure feeds, and is superior to that for CA based on a practical combined acid gas separation efficiency metric that we introduce. Finally, methods for continued development of the current polyimide membrane material for aggressive sour gas separations are presented.

► We test permeation and sorption properties of 6FDA-DAM:DABA (3:2) dense films.
► Pure and mixed gases comprised of H2S, CO2 and CH4 are used to simulate sour gas.
► Mixed gas results give major improvements to H2S/CH4 selectivity over pure gas.
► We report enhanced CO2/CH4 selectivity in the presence of low H2S partial pressure.
► Our polyimide performs well compared to other materials, and paths forward exist.