Surface segregation of fluorinated modifying macromolecule for hydrophobic/hydrophilic membrane preparation and application in air gap and direct contact membrane distillation

A fluorinated surface modifying macromolecule (SMM) was synthesized and blended into the casting solution of polyetherimide used as host polymer. A composite porous hydrophobic/hydrophilic membrane was prepared by the phase inversion technique in a single casting step. The membrane was characterized by different techniques. During membrane formation, SMM migrates to the top membrane surface increasing its hydrophobicity and decreasing its pore size, nodule size and roughness parameters. The thickness of the porous hydrophobic top layer was found to be around 4 μm. The membrane was used for desalination by air gap membrane distillation and direct contact membrane distillation. The experiments were performed for different sodium chloride aqueous solutions and various operating conditions. The water production rate was found to be high for direct contact membrane distillation because of the low resistance to mass transport achieved by the diminution of the water vapour transport path length through the hydrophobic thin top-layer of the membrane.

Migration of fluorinated surface modifying macromolecule (SMM) to the air/polymer interface and formation of porous composite hydrophobic/hydrophilic membrane.Figure optionsDownload high-quality image (328 K)Download as PowerPoint slideHighlights
► Synthesis of a fluorinated surface modifying macromolecule (SMM) and blend with polyetherimide.
► SMM migrates to the top membrane surface during membrane formation by phase inversion method.
► Composite porous hydrophobic/hydrophilic membrane was prepared using SMM and polyethermide.
► The hydrophobic top layer has a thickness of about 4 μm with a smooth surface and nano-metric pore size.
► The hydrophobic/hydrophilic membrane was applied for desalination by air gap and direct contact MD.