کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
635029 1456084 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Role of organic diluents on Am(III) extraction and transport behaviour using N,N,N′,N′-tetraoctyl-3-oxapentanediamide as the extractant
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Role of organic diluents on Am(III) extraction and transport behaviour using N,N,N′,N′-tetraoctyl-3-oxapentanediamide as the extractant
چکیده انگلیسی

Diluent effect on the solvent extraction and membrane transport properties of Am(III) using TODGA (N,N,N′,N′-tetraoctyl-3-oxapentanediamide) as extractant/carrier have been investigated in detail. The diluents studied were n-dodecane, 1-octanol, tert-butyl benzene, kerosene, toluene, carbon tetra chloride, chloroform, 1,2-dichloroethane, and nitrobenzene. The distribution ratio values of Am(III) with TODGA as the extractant were correlated with various diluent parameters. The nature of the extracted species formed was also determined for the different diluents. Supported liquid membrane (SLM) transport studies were carried out and the ease of Am transport followed the trend: toluene > n-dodecane > kerosene > 1-octanol > tert-butyl benzene ∼ CCl4 > CHCl3. Effect of membrane pore size on Am(III) transport for each of the diluents have been evaluated. Membrane diffusion coefficient values have been calculated using Wilke–Chang equation and compared with those determined experimentally using a tlag method.


► The nature of the diluents played a significant role in Am extraction and transport.
► The nature of the extracted species changed with the diluents.
► Membrane diffusion co-efficient were calculated and determined experimentally.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volumes 403–404, 1 June 2012, Pages 71–77
نویسندگان
, , , , ,