کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
636279 | 1456117 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New method to determine diffusion coefficients and surface rate constants in mixed ionic electronic conductors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: New method to determine diffusion coefficients and surface rate constants in mixed ionic electronic conductors New method to determine diffusion coefficients and surface rate constants in mixed ionic electronic conductors](/preview/png/636279.png)
چکیده انگلیسی
A new mathematical method to estimate diffusion coefficients (D) and surface rate constants (k) in mixed ionic electronic conductors has been developed. The so-called intersection line method neglects the dependency of D and k pairs on initial values like classical optimization programs do. The important advantages of the new developed method against classical optimization procedures in terms of independence of initial values and precision by finding the physically meaningful solution have been shown.
Research highlights▶ Characterization of mixed ionic electronic conductors. ▶ Investigations in kinetic processes in solid state. ▶ Mathematical modelling of diffusion processes. ▶ Optimization and parameter fitting.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 362, Issues 1–2, 15 October 2010, Pages 545–549
Journal: Journal of Membrane Science - Volume 362, Issues 1–2, 15 October 2010, Pages 545–549
نویسندگان
C. Elschner, M. Kusnezoff, S. Ziesche, A. Paepcke, A. Michaelis,