کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
636652 1456138 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and hydrogen permeation of SrCe0.95Y0.05O3−δ asymmetrical membranes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Preparation and hydrogen permeation of SrCe0.95Y0.05O3−δ asymmetrical membranes
چکیده انگلیسی

Asymmetrical thin membranes of SrCe0.95Y0.05O3−δ (SCY) were prepared by a conventional and cost-effective dry pressing method. The substrate consisted of SCY, NiO and soluble starch (SS), and the top layer was the SCY. NiO was used as a pore former and soluble starch was used to control the shrinkage of the substrate to match that of the top layer. Crack-free asymmetrical thin membranes with thicknesses of about 50 μm and grain sizes of 5–10 μm were successfully pressed on to the substrates. Hydrogen permeation fluxes (JH2JH2) of these thin membranes were measured under different operating conditions. At 950 °C, JH2JH2 of the 50 μm SCY asymmetrical membrane towards a mixture of 80% H2/He was as high as 7.6 × 10−8 mol/cm2 s, which was about 7 times higher than that of the symmetrical membranes with a thickness of about 620 μm. The hydrogen permeation properties of SCY asymmetrical membranes were investigated and activation energies for hydrogen permeation fluxes were calculated. The slope of the relationship between the hydrogen permeation fluxes and the thickness of the membranes was −0.72, indicating that permeation in SCY asymmetric membranes was controlled by both bulk diffusion and surface reaction in the range investigated.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 340, Issues 1–2, 15 September 2009, Pages 241–248
نویسندگان
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