کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
636978 | 1456145 | 2009 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fundamental investigations of the effect of the linkage group on the behavior of hydrophilic-hydrophobic poly(arylene ether sulfone) multiblock copolymers for proton exchange membrane fuel cells
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Fundamental investigations of the effect of the linkage group on the behavior of hydrophilic-hydrophobic poly(arylene ether sulfone) multiblock copolymers for proton exchange membrane fuel cells Fundamental investigations of the effect of the linkage group on the behavior of hydrophilic-hydrophobic poly(arylene ether sulfone) multiblock copolymers for proton exchange membrane fuel cells](/preview/png/636978.png)
چکیده انگلیسی
A growing number of alternative proton exchange membrane (PEM) research efforts involve multiblock copolymer chemistries, but little emphasis is placed on the methods used to couple the oligomers. Fluorinated linkage groups can help increase block efficiency during coupling, but their effect on a PEM is not well known. The choice of linkage type, hexafluorobenzene (HFB) vs. decafluorobiphenyl (DFBP), appears to have small but observable influences on multiblock copolymers with disulfonated and unsulfonated poly(arylene ether sulfone) oligomers. DFBP linkages promote greater phase separation than HFB linkages, resulting in increased stiffness, decreased ductility, and increased proton conductivity at low humidities. DFBP linkages also promote more surface enrichment of fluorine, causing changes in surface morphology and slightly increased water desorption, but determining the impact on actual fuel cell performance requires further research.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 333, Issues 1â2, 1 May 2009, Pages 1-11
Journal: Journal of Membrane Science - Volume 333, Issues 1â2, 1 May 2009, Pages 1-11
نویسندگان
Anand S. Badami, Ozma Lane, Hae-Seung Lee, Abhishek Roy, James E. McGrath,