کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
640768 1456975 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sorption of enantiomers and alcohols into Nafion® and the role of air humidity in the experimental data evaluation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Sorption of enantiomers and alcohols into Nafion® and the role of air humidity in the experimental data evaluation
چکیده انگلیسی


• The sorption experiments with Nafion + enantiomer systems.
• The structure of Nafion studied by 19F MASS NMR spectrum.
• The changes of weight of “dry” Nafion caused by various relative humidity RH.

Two enantiomers may exhibit completely different biological or pharmacological activities; therefore, the resolution of the enantiomers from a racemic mixture is an important task. The results of the total sorption measurements for the individual (+) and (−) liquid enantiomers from the enantiomeric pair revealed that there is a difference between extents of their sorption in Nafion®. The difference between liquid sorption of the (+) and (−) enantiomers of small molecules, such as the methyl lactates or 2-butanols, is higher than in the case of larger molecules, such as phenylethanols and methylbenzyl amines. This result could be explained by the hypothesis that the size of the chiral molecule must fit like a puzzle piece into the Nafion® helical polymer network. This hypothesis was supported by the 19F MAS NMR analysis, which confirmed the helical structure of Nafion®. Further, the branching of the molecules significantly influences the extent of sorption of the liquid in Nafion®, as shown for the butanols. The trend of this dependence is in agreement with the trend of heat of vaporisation and the normal boiling temperature data of the butanols. Because Nafion® easily absorbs water vapour from the air, the influence of the humidity on the sorption values was studied and discussed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 144, 15 April 2015, Pages 232–239
نویسندگان
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