|کد مقاله||کد نشریه||سال انتشار||مقاله انگلیسی||ترجمه فارسی||نسخه تمام متن|
|64520||48361||2016||10 صفحه PDF||سفارش دهید||دانلود رایگان|
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• Monomeric and oxodimeric species of catalyst may be responsible of its activity.
• Kinetic parameters of α-pinene oxidation were determined using genetic algorithm.
• A kinetic model based on the LHHW mechanism adequately fit the experimental data.
• The reaction mechanism involves homogeneous and heterogeneous pathways.
The kinetic of α-pinene oxidation over an iron hexadecachlorinated phthalocyanine immobilized on modified silica (FePcCl16-NH2-SiO2) with t-butyl hydroperoxide (TBHP) as oxidant is proposed. Reaction rates were calculated by the initial reaction rate method from the data obtained in a batch reactor, and compared with kinetic expressions proposed from mechanisms based on Langmuir Hinshelwood Hougen Watson (LHHW) and power-rate law models. The kinetic parameters were estimated from the experimental data by optimization using the Genetic Algorithm. A kinetic expression based on LHHW model with the adsorption of α-pinene, TBHP and the main reaction products (verbenone, α-pinene epoxide and verbenol) on the surface of the catalyst predicted the experimental data with good accuracy (R2 = 0.986). The apparent activation energy of α-pinene allylic oxidation over FePcCl16-NH2-SiO2/TBHP was 40.08 kJ/mol. α-Pinene conversion of 83.7% was obtained after 23 h with a selectivity to verbenone of 23%. Under the reaction conditions leaching of the active species was not observed; however, the effect of radicals in the bulk liquid phase was demonstrated, confirming that the reaction involves a combination of both heterogeneous and homogeneous pathways. The catalyst can be used at least in seven cycles without loss of α-pinene conversion nor verbenone selectivity.
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Journal: Journal of Molecular Catalysis A: Chemical - Volume 423, November 2016, Pages 12–21