کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6455165 | 1419023 | 2016 | 4 صفحه PDF | دانلود رایگان |
- Dicarboxylic-functionalized arylhydrazone of dimedone
- 1D Zn(II)-coordination polymer
- Homogeneous pre-catalyst for the diastereoselective Henry reaction in water
Reaction of a new hydrazone of β-diketone, 5-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)isophthalic acid (H3L), with zinc(II) nitrate hexahydrate in a mixture of DMF and water (1:1) under hydrothermal conditions affords the 1D coordination polymer [Zn(μ3-HL)(H2O)2]n â nH2O (1), where one of the carboxylic groups links two Zn(II) centers in a bridging bidentate (syn-syn-type) mode and the remaining one ligates a third metal cation in a monodentate fashion. It was characterized by IR and NMR spectroscopies, ESI-MS, elemental and single-crystal X-ray crystal structural analyses. 1 acts as an efficient pre-catalyst for the Henry reaction at 40 °C in aqueous medium, providing β-nitroalcohols with good yields (67-86%) and diastereoselectivities (syn:anti 77:23-69:31).
Journal: Catalysis Communications - Volume 87, 5 December 2016, Pages 49-52