کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6502876 | 1418996 | 2018 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biocatalytic conversion of 5-hydroxymethylfurfural: Synthesis of 2,5-bis(hydroxymethyl)furan and 5-(hydroxymethyl)furfurylamine
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two different green biocatalytic methods were investigated for the transformation of 5-hydroxymethylfurfural (HMF) to valuable disubstituted furan derivatives. 2,5-bis(hydroxymethyl) furan (BHMF) was obtained by biocatalytic reduction using lyophilized plant tissues. 5-(hydroxymethyl)furfurylamine (HMFA) was synthesized by amination transfer reaction catalysed by immobilized transaminase enzymes. By choosing suitable reaction conditions both products were obtained with high yields in water as reaction medium, at room temperature or 50â¯Â°C within a reaction time of 48 and 24â¯h. The studied protocols represent environmentally benign and promising green catalytic processes, generating less waste than other synthetic approaches.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 114, August 2018, Pages 15-18
Journal: Catalysis Communications - Volume 114, August 2018, Pages 15-18
نویسندگان
Antonella Petri, Giulia Masia, Oreste Piccolo,