کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6503461 46816 2014 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Mechanism of photocatalytic oxidation of guanine by BiOBr under UV irradiation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Mechanism of photocatalytic oxidation of guanine by BiOBr under UV irradiation
چکیده انگلیسی
This article analyzes the mechanism details of guanine photocatalytic oxidation on the surface of BiOBr nanoparticles under UV irradiation. The reaction of O2− with radical species, generated from primary oxidation of guanine by hole, is proposed to be the dominant cause of guanine damage. The present work demonstrates that BiOBr photocatalysis provided good model to investigate the reaction of substrate radical with the in situ formed O2−. It also implicates that the frequently-used biomarker for DNA damage 8-oxo-7,8-dihydro-2-deoxyguanosine (8-oxodG) may be ineffective in the situation that damage is caused by O2−.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 48, 10 March 2014, Pages 65-68
نویسندگان
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