کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6588827 1423243 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic prediction of the solvent effect on a transesterification reaction
ترجمه فارسی عنوان
پیش بینی ترمودینامیکی اثر حلال بر روی واکنش ترانس اکسیداسیون
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
In this work we re-evaluated the experimental data and now present a thermodynamic approach to consistently predict the solvent effect on both, the reaction equilibrium and the reaction kinetics. Accounting for the activity coefficients of the reactants/products obtained from the Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) allowed for considering the interactions of the reactants/products among themselves and also with the solvent heptane. Accounting for those, it is shown that the solvent effect on the reaction equilibrium as well as on the reaction rate can even be predicted in very good agreement with the experimental data.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 176, 2 February 2018, Pages 264-269
نویسندگان
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