کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6591185 | 456865 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Continuously operated miniplant for the rhodium catalyzed hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system (TMS)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Continuously operated miniplant for the rhodium catalyzed hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system (TMS) Continuously operated miniplant for the rhodium catalyzed hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system (TMS)](/preview/png/6591185.png)
چکیده انگلیسی
The hydroformylation of alkenes is one of the most important homogeneously catalyzed processes. However, a process with easy and efficient rhodium catalyst separation and fast reaction rates obtained by homogeneous conditions is not established for long chain alkenes so far. The application of thermomorphic solvent systems (TMS) is a promising concept which provides an innovative solution for both problems. In this work, a fully automated continuous process for the hydroformylation of 1-dodecene with special regard to an efficient catalyst recycling is designed and investigated. By means of the miniplant technique long term investigation of catalyst stability is possible in the early phase of process development. Operating continuously provides a simultaneous consideration of all recycle streams in the process in order to locate accumulation of impurities and byproducts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 115, 1 August 2014, Pages 88-94
Journal: Chemical Engineering Science - Volume 115, 1 August 2014, Pages 88-94
نویسندگان
M. Zagajewski, A. Behr, P. Sasse, J. Wittmann,