کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6591193 | 456865 | 2014 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Towards a novel process concept for the hydroformylation of higher alkenes: Mini-plant operation strategies via model development and optimal experimental design
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کلمات کلیدی
Bicontinuous phase1-dodeceneTDCDOCABICCATISO - ایزوIsomerization - ایزومریزاسیونOptimization - بهينه سازيEquilibrium - تعادلSeparations - جداسازیDodecane - داودانdoce - دوازدهOil - روغنProcess systems - سیستم های فرآیندDynamic simulation - شبیه سازی پویاMathematical modeling - مدل سازی ریاضیOil phase - مرحله نفتReaction engineering - مهندسی واکنشHyd - هیدروژنCatalyst - کاتالیست
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
When developing a new process with expensive and dangerous reaction partners, it is often of interest to keep pilot plant operation time low. A model of the process can aid in achieving this goal. However, the model is generally prone to errors, and thus, leading to deviations from the actual operation. In this contribution, the focus is set on the modeling of a novel process concept for the hydroformylation of long-chained alkenes with particular interest laid on the three phase micellar system. Moreover, a methodology is presented to support operators in determining suitable operating policies for mini-plant operation. Two models of the core units, reactor and decanter, of the constructed mini-plant are presented and linked. With these, an operation policy for the minimization of model parameter uncertainty is determined.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Science - Volume 115, 1 August 2014, Pages 127-138
Journal: Chemical Engineering Science - Volume 115, 1 August 2014, Pages 127-138
نویسندگان
David Müller, Duc Hoang Minh, Victor Alejandro Merchan, Harvey Arellano-Garcia, Yasemin Kasaka, Michael Müller, Reinhard Schomäcker, Günter Wozny,