کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6594464 | 1423666 | 2018 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Kinetics of thiophene hydrodesulfurization over a supported Mo-Co-Ni catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this study, the kinetics of thiophene (TH) hydrodesulfurization (HDS) over the Mo-Co-Ni-supported catalyst was investigated. Trimetallic catalyst was synthesized by pore volume impregnation and the metal loadings were 11.5 wt % Mo, 2 wt % Co, and 2 wt % Ni. A large surface area of 243 m2/g and a relatively large pore volume of 0.34 cm3/g for the fresh Mo-Co-Ni-supported catalyst indicate a good accessibility to the catalytic centers for the HDS reaction. The acid strength distribution of the fresh and spent catalysts, as well as for the support, was determined by thermal desorption of diethylamine (DEA) with increase in temperature from 20 to 600 °C. The weak acid centers are obtained within a temperature range between 160 and 300 °C, followed by medium acid sites up to 440 °C. The strong acid centers are revealed above 440 °C. We found a higher content of weak acid centers for fresh and spent catalysts as well as alumina as compared to medium and strong acid sites. The catalyst stability in terms of conversion as a function of time on stream in a fixed bed flow reactor was examined and almost no loss in the catalyst activity was observed. Consequently, this fact demonstrated superior activity of the Mo-Co-Ni-based catalyst for TH HDS. The activity tests by varying the temperature from 200 to 275 °C and pressure from 30 to 60 bar with various space velocities of 1-4 hâ1 were investigated. A Langmuir-Hinshelwood model was used to analyze the kinetic data and to derive activation energy and adsorption parameters for TH HDS. The effect of temperature, pressure, and liquid hourly space velocity on the TH HDS activity was studied.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 21, Issues 3â4, MarchâApril 2018, Pages 277-287
Journal: Comptes Rendus Chimie - Volume 21, Issues 3â4, MarchâApril 2018, Pages 277-287
نویسندگان
Rami Doukeh, Mihaela Bombos, Ancuta Trifoi, Oana Mihai, Daniela Popovici, Ion Bolocan, Dorin Bombos,