کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6630289 | 1424931 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Application of featured microwave-metal discharge for the fabrication of well-graphitized carbon-encapsulated Fe nanoparticles for enhancing microwave absorption efficiency
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Carbon-encapsulated iron nanoparticles (Fe@CNPs) with a high degree of graphitization, good integrity in the graphite shells, and high microwave-absorbing capability were prepared by first dissolving ferrocene into organic solvent and then being carbonized by MW-metal discharges under inert atmosphere. Four different organic solvents (benzene, cyclohexane, paraffin, and anhydrous ethanol) were tested, and well-graphitized Fe@CNPs were formed when using benzene or cyclohexane as the solvent. The use of MW-metal discharges with low-toxic cyclohexane and ferrocene as raw materials provides a new method for the preparation of Fe@CNPs with the merits of simplicity, low environmental impact, and high efficiency. The fabricated Fe@CNPs have excellent microwave-absorbing capability, which is respectively 29, 19.3, and 9.7 times those of carbonyl iron powder, SiC, and carbon nanotubes after 1-min microwave irradiation at 1000â¯W. The thermal gravimetric analysis demonstrates that the fabricated Fe@CNPs have good thermal stability. Owing to these properties, Fe@CNPs have the potential to shape nanoscale or micron scale high-energy sites for a vast variety of applications in the field of microwave chemistry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 233, 1 December 2018, Pages 669-676
Journal: Fuel - Volume 233, 1 December 2018, Pages 669-676
نویسندگان
Jing Sun, Yican Wang, Wenlong Wang, Ke Wang, Jiaxin Lu,