کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
6630981 1424939 2018 7 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
Deep desulfurization of fuels with cobalt chloride-choline chloride/polyethylene glycol metal deep eutectic solvents
ترجمه فارسی عنوان
سولفوریزاسیون عمیق سوخت با کلرید کبالت-کولین کلرید / پلی اتیلن گلیکول حلال های عمیق یوتکتیک عمیق
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Deep eutectic solvents (DESs) are receiving increasing attention as ionic liquid analogues because of their environmentally friendly and very low-price characteristics. In this study, metal-based deep eutectic solvents (MDESs) were synthesized by combining cobalt chloride (CoCl2), a hydrogen bond acceptor (HBA) such as choline chloride (ChCl), and hydrogen bond donors (HBDs) such as polyethylene glycol (PEG-200), ethylene glycol (EG), glycerol (GL), and propionic acid (Pr). The MDESs were used for the extractive catalytic oxidative desulfurization (ECODS) of fuels. Solid peroxymonosulfate (PMS) was selected as an oxidant over common ECODS oxidants such as liquid hydrogen peroxide because the former is cheaper, more stable, and less corrosive. The MDESs played dual roles (i.e., extractant and catalyst) during the ECODS process. One of the MDESs prepared (CoCl2-ChCl/2PEG) showed fast reaction rates with nearly 100% dibenzothiophene removal under the optimal conditions (6 g of model oil with an initial sulfur content of 500 ppm, 0.9 g of PMS solution, 2 g of CoCl2-ChCl/2PEG, 20 °C, and 60 min). The DESs prepared showed an outstanding recycling performance after 6 cycles without a significant decrease in activity. In the ECODS system, the reactivity of the three sulfur substrates studied followed the order: dibenzothiophene (DBT) > 4,6-dimethyldibenzothiphene (4,6-DMDBT) > benzothiophene (BT). In the case of the HBDs, the desulfurization efficiencies followed the sequence: PEG-200 > Pr > EG > GL. The oxidative product was dibenzothiophene sulfone (DBTO2).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 225, 1 August 2018, Pages 104-110
نویسندگان
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