Investigation of ammonia removal from the simulated producer gas of biomass gasification by H2-reduced titanomagnetite

The experimental results show that in the control Ar gas, the H2-reduced titanomagnetite had much higher activity than the unprocessed titanomagnetite to decompose NH3 at all of the temperatures tested, and the efficiency of NH3 removal increased with reaction temperature. The NH3 decomposition by the reduced titanomagnetite was 97.8% at 500 °C, 99.7% at 600 °C, and 100% at 750 and 850 °C, in comparison with corresponding values of 31.6%, 34.0%, 83.9% and 93.2% for the unprocessed titanomagnetite. Therefore, the H2-reduced titanomagnetite was then employed to remove NH3 in the simulated producer gas in which the NH3 decomposition was 28.4 ± 3.4%, 94.7 ± 2.8% and 98.4 ± 0.4%, respectively, at 500, 750 and 850 °C. In NH3 decomposition in the simulated gas, side reactions have been identified and analysed which played different roles at different temperatures and also affected the gas composition. At 500 °C, the carbon formation from the Boudouard reaction significantly suppressed the activity of the reduced titanomagnetite for NH3 decomposition.