Dimensionally reduced modeling of nitric oxide formation for premixed methane-air flames with ammonia content

The numerical analysis results were in a good agreement with the experimental results for the lean mixtures and ammonia content up to 1% for all investigated combustion models and the kinetic reaction mechanisms. Trends of the nitric oxide emission obtained with the stoichiometric flames were valid for 1D models. However overall values were over predicted for an adiabatic 1D FreeFlame calculations and under predicted for 1D BurnerFlame, which showed a sensitivity of the nitrogen chemistry to the process temperature. Analysis with the 3D Ansys EDC model and GRI 3.0 provided the most accurate results up to 2.5% of the NH3 share in the fuel with a maximum relative differences values to the experimental results from 10% up to 24% for the lean and the stoichiometric conditions respectively.