کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6643047 461175 2013 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A microscopic study of the precipitation of metallic iron in slag from iron-rich coal during high temperature gasification
ترجمه فارسی عنوان
بررسی میکروسکوپی بارگیری آهن فلزی در سرباره از زغال سنگ غنی شده در طول گازسیون درجه حرارت بالا
کلمات کلیدی
ریزساختاری سرباره، بارش آهن فلزی، گاز زغال سنگ، استفاده از سرباره،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
The behavior of iron in molten slag from iron-rich coal during high temperature gasification conditions was studied. The proportion of crystalline phase in the slag was measured by X-ray diffraction (XRD) and the microstructure of the slag was quantitatively analyzed by CCSEM. Metal ions in acid-digested slag samples were analyzed by ICP-AES. It was confirmed that the precipitation and settling processes of metallic iron in slag were significantly affected by both the atmosphere and the reaction temperature. In a strongly reducing atmosphere such as 10/90 (vol%) mixtures of CO2/H2, the Fe content of bulk slag was reduced due to the precipitation of metallic iron in molten slag below 1550 °C. The profile of the iron content of the slag was related to the dissolved oxygen transfer in molten slag. At temperatures higher than that of the equilibrium reaction of FeO (slag) = Fe (l) + [O] (slag), metallic iron is no longer precipitated and the slag becomes a homogeneous phase. In addition, some heavy metals showed the same behavior as iron in the strongly reducing atmosphere were extracted by 1M/HCl, which results in higher extraction rates for Fe, Mg, Zn, and Pb.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 103, January 2013, Pages 101-110
نویسندگان
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