کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6679471 | 1427927 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modelling of aromatics and soot formation from large fuel molecules
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Modelling of aromatics and soot formation from large fuel molecules Modelling of aromatics and soot formation from large fuel molecules](/preview/png/6679471.png)
چکیده انگلیسی
There is a need for prediction models of soot particles and polycyclic aromatic hydrocarbons (PAHs) formation in parametric conditions prevailing in automotive engines: large fuel molecules and high pressure. A detailed kinetic mechanism able to predict the formation of benzene and PAHs up to four rings from C2 fuels, recently complemented by consumption reactions of decane, was extended in this work to heptane and iso-octane oxidation. Species concentrations measured in rich, premixed flat flames and in a jet stirred reactor (JSR) were used to check the ability of the mechanism to accurately predict the formation of C2 and C3 intermediates and benzene at pressures ranging from 0.1 to 2.0Â MPa. Pathways analyses show that propargyl recombination is the only significant route to benzene in rich heptane and iso-octane flames. When included as the first step of a soot particle formation model, the gas-phase kinetic mechanism predicts very accurately the final soot volume fraction measured in a rich decane flame at 0.1Â MPa and in rich ethylene flames at 1.0 and 2.0Â MPa.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Proceedings of the Combustion Institute - Volume 32, Issue 1, 2009, Pages 753-759
Journal: Proceedings of the Combustion Institute - Volume 32, Issue 1, 2009, Pages 753-759
نویسندگان
Caroline Marchal, Jean-Louis Delfau, Christian Vovelle, Gladys Moréac, Christine Mounaı¨m-Rousselle, Fabian Mauss,