کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6713472 1428732 2018 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of calcium leaching on chloride diffusivity in cement-based materials
ترجمه فارسی عنوان
تأثیر چسبندگی کلسیم بر انتشار مواد کلر در مواد سیمان
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی عمران و سازه
چکیده انگلیسی
The coupling action of calcium leaching and chloride attack is an important durability problem for the cement-based materials served in long-termly in the environmental water like seawater or groundwater containing chloride. This paper investigates the influence of calcium leaching on the chloride diffusivity in cement-based materials by the corrosion experiment, in which the hardened cement paste (HCP) specimens are immersed into three corrosion solutions with the same chloride concentration, such as 1 M sodium chloride solution, 1 M ammonium chloride solution and the mixed solution of 1 M sodium chloride and 3 M ammonium nitrate. Some measurements, like the phenolphthalein, saturation-drying weighing, mercury intrusion porosimetry (MIP), Scanning Electron Microscopy (SEM/EDS), X-ray diffraction analysis (XRD) and rapid chloride test (RCT), are used to analyze the leaching behaviors and its influence on the chloride diffusivity of HCP, characterized by leaching depth, pore structure, morphology, calcium-silicon ratio, chloride-silicon ratio, phase composition and free chloride ion content. Results show that, in the calcium leaching process, the compactness, calcium hydroxide content and calcium-silicon ratio of C-S-H gel of HCP decreases with the leaching time. The calcium leaching causes the reduction of the physically chloride-bound ability and the chemically chloride-absorbed ability in HCP, and it results in high chloride diffusivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Construction and Building Materials - Volume 174, 20 June 2018, Pages 310-319
نویسندگان
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