کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6715147 | 1428740 | 2018 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effects and mechanisms of surface-treatment of cementitious materials with nanoSiO2@PCE core-shell nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی عمران و سازه
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چکیده انگلیسی
A commercial interest in the improvement of durability is driving efforts to develop new generation of surface-treatment agents. In the previous paper, a series of nanoSiO2-polycarboxylate superplasticizer core-shell nanoparticles (NS@PCE) were synthesized by “grafting to” method. In this paper, we aim to explore the potential of NS@PCE to densify the surface of cementitious materials, and to study the mechanism of nanoparticles surface-treatment process by measuring water absorption ratio, dispersion stability, pozzolanic reactivity, and mercury intrusion porosimetry. Results show that NS@PCE is effective in reducing the water absorption. Various NS@PCE present different influences, it seems that NS@PCE with a moderate shell-core ratio is a more reasonable choice. A hypothesis was proposed to explain the surface-treatment effect of nanoparticles, it utilizes two properties (dispersity and pozzolanic reactivity) of nanoparticles to describe their refining-pore performance. This research indicates a new pathway for nanoSiO2 to optimizing cementitious materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Construction and Building Materials - Volume 166, 30 March 2018, Pages 12-22
Journal: Construction and Building Materials - Volume 166, 30 March 2018, Pages 12-22
نویسندگان
Yue Gu, Qianping Ran, Wei She, Xin Shu, Jiaping Liu,