کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
674687 1459572 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermogravimetric analysis-mass spectrometry (TG-MS) of selected Chinese palygorskites—Implications for structural water
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Thermogravimetric analysis-mass spectrometry (TG-MS) of selected Chinese palygorskites—Implications for structural water
چکیده انگلیسی

Four Chinese palygorskites clay minerals have been analysed by thermogravimetric analysis-mass spectrometry and X-ray diffraction. The structural water of the palygorskite dehydrates in the temperature range of 30–625 °C, as shown in the thermogravimetric analysis and mass spectrometric curves. The mass spectrometric curves combined the differential thermogravimetric curves enable the detailed determination of the main dehydration steps. The results show that the dehydration occurs in four main steps: (a) elimination of interparticle water and partial zeolitic water at below 110 °C, (b) release of the rest part of zeolitic water from the structural layer of palygorskite at about 160 °C, (c) dehydration of one part of bound water at about 340 °C and (d) loss of the rest part of bound water at around 450 °C. The temperatures of dehydration of the palygorskite minerals are found to be influenced by the geological environment and the amount and kind of impurities. The evolved gases in the decomposition process are various because of the different amounts and kind of impurities. It is also found that decarbonization takes place at around 600 °C due to the decomposition of calcite and dolomite impurities in these minerals. It is evident by the mass spectrometric curve that the water is given out from the samples and carbon dioxide originates from the impurity calcite and dolomite.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 512, Issues 1–2, 10 January 2011, Pages 202–207
نویسندگان
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