کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
674836 1459576 2010 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic and acoustic properties of binary mixtures of oxolane with aniline and substituted anilines at 303.15, 313.15 and 323.15 K
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Thermodynamic and acoustic properties of binary mixtures of oxolane with aniline and substituted anilines at 303.15, 313.15 and 323.15 K
چکیده انگلیسی

Speeds of sound u, isentropic compressibilities κS, Rao's molar sound functions R, intermolecular free lengths Lf, specific acoustic impedances Z  , excess molar volumes VmE, excess isentropic compressibilities κSE, excess intermolecular free lengths LfE and excess specific acoustic impedances ZE, of three binary mixtures of oxolane (tetrahydrofuran) with aniline, N-methylaniline and N-ethylaniline have been reported over the entire range of composition at 303.15, 313.15 and 323.15 K. The excess values have been fitted to Redlich–Kister polynomial equation. The results have been analyzed in terms of molecular interactions between oxolane and anilines. The speeds of sound in present binary mixtures have been estimated from various empirical and theoretical models.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volumes 507–508, 10 August 2010, Pages 27–34
نویسندگان
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