کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
675484 1459622 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pyrolysis of carbonaceous foundry sand additives: Seacoal and gilsonite
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
Pyrolysis of carbonaceous foundry sand additives: Seacoal and gilsonite
چکیده انگلیسی

Seacoal and gilsonite are used by the foundry industry as carbonaceous additives in green molding sands. In this study, pyrolysis was used to simulate the heating conditions that the carbonaceous additives would experience during metal casting. Gas chromatography–mass spectrometry was used to tentatively identify major organic products generated during their pyrolysis at 500, 750, and 1000 °C. A number of compounds of environmental concern were identified during the pyrolysis of seacoal and gilsonite, including substituted benzenes, phenolics, and polycyclic aromatic hydrocarbons (PAHs). These thermal decomposition products, and especially PAHs, were generated at each pyrolysis temperature in all foundry sands containing seacoal. In gilsonite-amended sand, however, mainly alkanes and alkenes were identified at 500 and 750 °C and PAHs at 1000 °C. Compared to seacoal, the most intense peaks occurred during the pyrolysis of sand containing gilsonite. The greatest loss of pyrolyzable material also occurred during heating of gilsonite-amended sand from ambient temperature to 1000 °C in a thermogravimetric analyzer. The results obtained from this study will be useful to green sand foundries looking to reduce volatile hydrocarbon emissions.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 460, Issues 1–2, 25 August 2007, Pages 60–66
نویسندگان
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