Light mirror reflection combined with heating/cooling curves as a method of studying phase transitions in transparent and opaque petroleum products: Apparatus and theory

A portable low weight low cost apparatus “Phasafot” and method for determining pour and cloud points of petroleum products, as well as precipitation and melting temperatures of paraffins in both transparent (diesel fuels), semi-transparent (lube oils) and opaque (crude oils) samples are described. The method consists in illuminating the surface of a sample with an oblique light beam and registering the intensity of specularly reflected light while heating/cooling the sample in the temperature range of its structural transitions. The mirror reflection of a light beam from an ideally smooth liquid surface falls in intensity when the surface becomes rough (dim) due to crystal formation. Simultaneous recording of the temperature ramp curve and the mirror reflection curve enables the determination of the beginning and end of crystallization of paraffins in both transparent and opaque petroleum products. Besides, their rheological properties can be accurately determined by rocking or tilting the instrument while monitoring the sample movement via its mirror reflection.