Towards integrated biorefinery from dried distillers grains: Selective extraction of pentoses using dilute acid hydrolysis

• A process for selective extraction of pentoses from DDG was presented as a part of integrated biorefinery approach.
• The selectivity for pentoses was high using dilute acid hydrolysis in a percolation reactor with liquid recirculation.
• Pretreatment of DDG using screening and ultrasonication resulted in fractional increase of the pentose yield by 42 %.
• A 94% yield in pentoses (280.9 g kg−1 of DDG) was obtained.
• A 2-stage hydrolysis process, developed to extract individual pentoses, resulted in arabinose and xylose rich streams.

The abundant availability and high level of hemicellulose content make dried distillers grains (DDG) an attractive feedstock for production of pentoses (C5) and conversion of C5 to bioproducts. One target of this work was to produce a C5 extract (hydrolyzate) with high yield and purity with a low concentration of C5 degradation products. A high selectivity towards pentoses was achieved using dilute acid hydrolysis of DDG in a percolation reactor with liquid recirculation. Pretreatment of starting material using screening and ultrasonication resulted in fractional increase of the pentose yield by 42%. A 94% yield of pentoses on the DDG (280.9 g kg−1) was obtained. Selective extraction of individual pentoses has been achieved by using a 2-stage hydrolysis process, resulting in arabinose-rich (arabinose 81.5%) and xylose-rich (xylose 85.2%) streams. A broader impact of this work is towards an Integrated Bio-Refinery based on DDG – for production of biofuels, biochemical intermediates, and other bioproducts.