کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
692977 889859 2011 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Surface properties and moisture behaviour of pine and heat-treated spruce modified with alkoxysilanes by sol–gel process
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تکنولوژی و شیمی فرآیندی
پیش نمایش صفحه اول مقاله
Surface properties and moisture behaviour of pine and heat-treated spruce modified with alkoxysilanes by sol–gel process
چکیده انگلیسی

The surface morphology and moisture behaviour of pine (Pinus sylvestris) sapwood and heat-treated spruce (Picea abies) deposited with two types of silane-based sol–gel coatings were studied by atomic force microscopy (AFM) and water contact angle measurement. The chemical composition and distribution of sol–gel coatings on wood surfaces were investigated by X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The AFM images revealed that the sol–gel coatings applied by spreading covered the fine structure of the wood substrates. The surface roughness analysis of the AFM topographical images indicated that the sol–gel coatings, especially the one with short aliphatic chain, had a tendency to smooth the wood surface. The XPS results confirmed that the sol–gel coatings had successfully deposited onto pine sapwood and heat-treated spruce changing their surface chemistries. ToF-SIMS images showing Si ion distribution on treated surfaces revealed that the coatings fully covered pine sapwood surfaces. The thin coating layers formed on heat-treated spruce surfaces followed the original wood surface structure. The contact angle measurements indicated that the water repellent properties of both pine and heat-treated spruce were improved to certain extent by the sol–gel coatings.


► We developed two silane-based nano-hybrid coatings to improve the water repellent properties of pine sapwood and heat-treated spruce.
► We characterized the surface morphology and chemistry of the applied sol–gel coatings on pine sapwood and heat-treated spruce by AFM, XPS and ToF-SIMS.
► We studied the moisture behaviours of the wood samples and found out that the water repellence of both pine and heat-treated spruce were improved to certain extent by the applied coatings.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Organic Coatings - Volume 71, Issue 3, July 2011, Pages 274–282
نویسندگان
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