کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6967847 | 1453003 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Arsenic associated with gypsum produced from Fe(III)-As(V) coprecipitation: Implications for the stability of industrial As-bearing waste
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Gypsum is a high-volume by-product of hydrometallurgical arsenic removal using the Fe(III)-As(V) coprecipitation technique. However, the role of gypsum in As fixation during the Fe(III)-As(V) coprecipitation process and the potential risk of As-bearing gypsum are still not well known. In this study, the fixation of As by gypsum was quantitatively investigated as a function of the initial As and H2SO4 concentrations, Fe/As molar ratio, pH, and neutralization mode. Column leaching tests were also performed to evaluate the potential risk of Fe(III)-As(V) coprecipitates. The results showed that the gypsum isolated from Fe(III)-As(V) coprecipitates by ascorbic acid (VC) treatment could fix up to 4.5% of the total As in the system at pH 8 in fixed-pH mode. The gypsum produced in fixed-pH mode contained a significantly higher concentration of As than that produced in acid-alkaline neutralization mode. The column leaching tests showed that a faster leaching rate could enhance the release of As from Fe(III)-As(V) coprecipitates. It seems that the presence of gypsum could prevent the release of As from Fe(III)-As(V) coprecipitates. Linear combination fits of the As and Fe K-edge XANES spectra suggested that As was likely to occur as adsorbed As and yukonite in VC-isolated gypsum.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 360, 15 October 2018, Pages 311-318
Journal: Journal of Hazardous Materials - Volume 360, 15 October 2018, Pages 311-318
نویسندگان
Shaofeng Wang, Danni Zhang, Xiaoliang Li, Guoqing Zhang, Ying Wang, Xin Wang, Mario A. Gomez, Yongfeng Jia,