کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6970190 | 1453044 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Water-soluble lead in cathode ray tube funnel glass melted in a reductive atmosphere
ترجمه فارسی عنوان
سرب محلول در آب در فلاسک قرقره رادیویی کادمیوم در یک فاز کاهش یافته ذوب می شود
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کلمات کلیدی
لامپ پرتوی کاتدی، شیشه قرقره، کاهش ذوب، سرب محلول در آب،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
چکیده انگلیسی
In the reduction-melting process, lead can be recovered from cathode ray tube funnel glass (PbOÂ =Â 25Â wt%); however, resulting glass residues still contain approximately 1-2Â wt% of unrecovered lead. For environmental protection in the residue disposal or recycling, it is important to evaluate the quantities of water-soluble species among the unrecovered lead. This study examined water-soluble lead species generated in the reduction-melting process of the funnel glass and factors determining their generation. In the reduction-melting, metallic lead was generated by reducing lead oxides in the glass, and a part of the metallic lead remained in the glass residue. Such unrecovered metallic lead can dissolve in water depending on its pH level and was regarded as water-soluble lead. When 10Â g Na2CO3 was added to 20Â g funnel glass during reduction-melting, the resulting glass contained high concentrations of sodium. In a water leaching of the glass, the obtained leachate was alkalized by the sodium-rich glass (pHÂ =Â 12.7-13.0). The unrecovered metallic lead in the glass was extracted in the alkalized leachate. The quantity of the unrecovered metallic lead (water-soluble lead) in the glass decreased when the melting time, melting temperature, and carbon dosage were controlled during reduction-melting.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 316, 5 October 2016, Pages 43-51
Journal: Journal of Hazardous Materials - Volume 316, 5 October 2016, Pages 43-51
نویسندگان
Takashi Okada,