کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6971618 | 1453080 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Compound specific stable isotope analysis (CSIA) to characterize transformation mechanisms of α-hexachlorocyclohexane
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
A systematic investigation of environmentally relevant transformation processes of alpha-hexachlorocyclohexane (α-HCH) was performed in order to explore the potential of compound specific stable isotope analysis (CSIA) to characterize reaction mechanisms. The carbon isotope enrichment factors (ÉC) for the chemical transformations of α-HCH via direct photolysis, indirect photolysis (UV/H2O2), hydrolysis, electro-reduction or reduction by Fe0 were quantified and compared to those previously published for biodegradation. Hydrogen abstraction by hydroxyl radicals generated by UV/H2O2 led to ÉC of â1.9 ± 0.2â° with an apparent kinetic carbon isotope effect (AKIEC) of 1.012 ± 0.001. Dehydrochlorination by alkaline hydrolysis yielded ÉC of â7.6 ± 0.4â° with AKIEC of 1.048 ± 0.003. Dechlorination either by homolytic bond cleavage in direct photolysis (ÉC = â2.8 ± 0.2â°) or single-electron transfer in electro-reduction (ÉC = â3.8 ± 0.4â°) corresponded to AKIEC of 1.017 ± 0.001 and 1.023 ± 0.003, respectively. Dichloroelimination catalyzed by Fe0 via two-electron transfers resulted in ÉC of â4.9 ± 0.1â°. AKIEC values assuming either a concerted or a stepwise mechanism were 1.030 ± 0.0006 and 1.015 ± 0.0003, respectively. Contrary to biodegradation, no enantioselectivity of α-HCH was observed in chemical reactions, which might be used to discriminate chemical and biological in situ transformations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 280, 15 September 2014, Pages 750-757
Journal: Journal of Hazardous Materials - Volume 280, 15 September 2014, Pages 750-757
نویسندگان
Ning Zhang, Safdar Bashir, Jinyi Qin, Janine Schindelka, Anko Fischer, Ivonne Nijenhuis, Hartmut Herrmann, Lukas Y. Wick, Hans H. Richnow,