کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7006465 1455157 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of ternary combined ZnO-Ag2O/porous g-C3N4 composite photocatalyst and enhanced visible-light photocatalytic activity for degradation of ciprofloxacin
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
Preparation of ternary combined ZnO-Ag2O/porous g-C3N4 composite photocatalyst and enhanced visible-light photocatalytic activity for degradation of ciprofloxacin
چکیده انگلیسی
In current work, a ternary combined ZnO-Ag2O/porous g-C3N4 (ZnO-Ag2O/pg-C3N4) composite photocatalyst was prepared and used for the degradation of ciprofloxacin (CIP) under visible light irradiation. The structure, surface morphology and chemical composition of as-prepared composite photocatalyst are investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL) and Brunauer-Emmett-Teller (BET) methods. From the DRS and PL optical property test, the result indicated that ZnO-Ag2O/pg-C3N4 presented relative narrow band gap and higher separation rate of photoinduced charge carriers in the ternary combined system, which was favorable for the photocatalytic activity enhancement under visible light irradiation. Compared with ZnO, porous g-C3N4, Ag2O and ZnO-Ag2O, the prepared ZnO-Ag2O/pg-C3N4 presents the highest degradation efficiency (97.4%) within 48 min. The degradation intermediates of CIP were detected by HPLC/MS during photocatalytic degradation. Furthermore, porous g-C3N4 as a visible-light-driven photocatalyst used as supporter in the combined system not only improves the degradation efficiency, but also speeds up the reaction rate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Research and Design - Volume 111, July 2016, Pages 253-261
نویسندگان
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