کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
700857 890944 2010 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Some novel aspects of nanocrystalline diamond nucleation and growth by direct current plasma assisted chemical vapor deposition
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Some novel aspects of nanocrystalline diamond nucleation and growth by direct current plasma assisted chemical vapor deposition
چکیده انگلیسی

Some novel aspects of nanocrystalline diamond (NCD) film nucleation and growth by DC-PACVD were investigated, which focused on the effect of methane injection timing at ramp stage (see discussion in the text) and cathode temperature as well. NCD films were deposited for 4 h on a 4 in. Si wafer which was ultrasonically seeded in a methanol slurry of diamond powder with a 5 nm average diameter. The H2/CH4/N2 gas mixture with a composition of 96.7%/3%/0.3% was used as precursor gas. The total gas flow rate and chamber pressure were 150 sccm and 150 Torr, respectively. Discharge voltage and current of 500 V and 45 A were used respectively at a substrate temperature of 800 °C. The nucleation density, microstructure, growth rate and crystallinity of the obtained NCD films were characterized by SEM, XRD, NEXAFS and Raman spectroscopy. The nucleation density was found to be sensitive to methane injection timing in the ramp stage. In addition, the cathode temperature greatly affected the nucleation density, grain size and growth rate.

Research Highlights
► The nucleation density was sensitive to the methane injection timing, which was attributed to the etching of the seeded diamond particle by hydrogen plasma in the ramp stage.
► The cathode temperature greatly affected nucleation density, grain size and growth rate, which was attributed to the carbon depletion to the cathode surface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Diamond and Related Materials - Volume 19, Issue 11, November 2010, Pages 1393–1400
نویسندگان
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