کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
701293 1460819 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High resolution electron energy loss spectroscopy of hydrogenated polycrystalline diamond: Assignment of peaks through modifications induced by isotopic exchange
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
High resolution electron energy loss spectroscopy of hydrogenated polycrystalline diamond: Assignment of peaks through modifications induced by isotopic exchange
چکیده انگلیسی

In this work we unambiguously determine the origin of the different peaks which appear in the High Resolution Electron Energy Loss Spectrum (HREELS) of hydrogenated polycrystalline diamond films for an incident electron energy of 5 eV and loss energies extending to 700 meV. High quality diamond films deposited by hot filament chemical vapor deposition from various isotopic gas mixtures: 12CH4 + H2, 12CD4 + D2, 12CH4 + D2, 12CD4 + D2, 13CH4 + H2 were characterized. The different vibrational modes, fundamentals and overtones, were directly identified through the modifications of the HREEL spectra induced by the isotopic exchange of H by D and 12C by 13C Three types of peaks were identified: (1) pure C–C related peaks (a diamond optical phonon at ∼ 155 meV and its overtones at 300, 450 and 600 meV), (2) pure C–H related peaks (C–H bend at ∼ 150 meV and C–H stretch of sp3 carbon at 360 meV), (3) coupling of C–H and C–C peaks (510 meV peak due to coupling of the C–H stretch at 360 meV with either the C–C stretch or the C–H bend at ∼ 155 meV). The overtones at 300, 450 and 600 meV (associated with electron scattering at diamond optical phonons) indicate a well defined hydrogenated diamond surface since they are absent in the HREEL spectrum of low energy ion beam damaged diamond surface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Diamond and Related Materials - Volume 16, Issues 4–7, April–July 2007, Pages 855–860
نویسندگان
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