کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7021670 | 1456023 | 2015 | 17 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Gas transport properties of reverse-selective poly(ether-b-amide6)/[Emim][BF4] gel membranes for CO2/light gases separation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The present research investigates deeply the effect of 1-ethyl-3 methylimidazolium tetrafluoroborate ([Emim][BF4]) ionic liquid on separation performance and transport properties of poly(ether-b-amide6) (Pebax1657) at different operating pressures from 2 to 20 bar and temperatures from 25 to 65 °C. [Emim][BF4] showed interesting separation factor for CO2/light gases as a solvent and it was expected that its addition to Pebax1657 leads to more amorphous structure, thereby increasing diffusion and permeability of gases. [Emim][BF4] was added to the polymer solution up to 100 wt% of Pebax1657 weight and permeation coefficients of CO2, H2, CH4 and N2 through the prepared membranes were measured. The results showed remarkable increment in permeation of all the tested gases, particularly CO2 and ideal selectivity of CO2/H2 enhanced significantly due to high solubility selectivity of the added compound. Effect of operating conditions on solubility coefficients was also investigated; thus sorption isotherms and activation energies of permeability, solubility and diffusion were calculated. In addition, the membranes were characterized by SEM, DSC, FT-IR spectroscopy and Tensile analysis to inspect changes in their physical and thermal properties, precisely.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 476, 15 February 2015, Pages 286-302
Journal: Journal of Membrane Science - Volume 476, 15 February 2015, Pages 286-302
نویسندگان
Hesamoddin Rabiee, Ali Ghadimi, Toraj Mohammadi,