کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7021823 | 1456028 | 2014 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of organic, colloidal and combined fouling on NF rejection of NaCl and carbamazepine: Role of solute-foulant-membrane interactions and cake-enhanced concentration polarisation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Influence of organic, colloidal and combined fouling on NF rejection of NaCl and carbamazepine: Role of solute-foulant-membrane interactions and cake-enhanced concentration polarisation Influence of organic, colloidal and combined fouling on NF rejection of NaCl and carbamazepine: Role of solute-foulant-membrane interactions and cake-enhanced concentration polarisation](/preview/png/7021823.png)
چکیده انگلیسی
The effects of single and combined fouling by sodium alginate, latex and Al2O3 on membrane performance in terms of permeate flux, salt rejection and rejection of the pharmaceutical carbamazepine were evaluated in a laboratory-scale cross-flow filtration unit. Fouling resulted in different extents in permeate flux, salt rejection and carbamazepine rejection over time. Combined fouling resulted in larger flux declines, and the influence of Ca2+ addition on flux was pronounced. In contrast, the influence of combined fouling and Ca2+ addition on salt and carbamazepine rejection was limited. Several hypotheses were tested to assess the influence of fouling on carbamazepine rejection. Relating observed rejection results to the solution-diffusion model revealed insight in whether the effect of fouling on rejection was mainly flux-driven or not. For most foulants, rejection declined less than what was predicted as a function of flux by the solution-diffusion model, indicating that CECP is not the main mechanism responsible for the decline in rejection upon fouling, especially not for latex fouling layers (regardless of the presence of Ca2+). This was corroborated by CECP modelling data. Solute-membrane interaction energies revealed that carbamazepine had higher affinity for the foulants than for the clean membrane surface. As such, it could be hypothesised that for most fouling layers, the relatively small decrease in carbamazepine rejection was mainly due to the decline in flux and the formation of a dense fouling layer on the membrane surface, which had some rejection properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 471, 1 December 2014, Pages 35-46
Journal: Journal of Membrane Science - Volume 471, 1 December 2014, Pages 35-46
نویسندگان
Mahlangu T.O., Hoek E.M.V., Mamba B.B., Verliefde A.R.D.,