کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7021943 | 1456028 | 2014 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facilitated separation of CO2 and SO2 through supported liquid membranes using carboxylate-based ionic liquids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Facilitated separation of CO2 and SO2 through supported liquid membranes using carboxylate-based ionic liquids Facilitated separation of CO2 and SO2 through supported liquid membranes using carboxylate-based ionic liquids](/preview/png/7021943.png)
چکیده انگلیسی
The facilitated separation of CO2 and SO2 in a series of supported ionic liquid membranes (SILMs) impregnated with carboxylate-based ILs (including monocarboxylates and dicarboxylates) was investigated systematically under humidified condition. The effects of transmembrane pressure difference and temperature on the permeability of acidic gases and permselectivity of gas pairs were studied. It is found that dicarboxylate-based ILs are a class of tunable media for the selective separation of acidic gases. When the anions of dicarboxylate-based ILs are fully deprotonated, they could be used as effective carriers for the selective separation of CO2. The permeabilities of CO2 in triethylbutylammonium malonate ([N2224]2[malonate]) and triethylbutylammonium maleate ([N2224]2[maleate]) under the partial pressure of 0.1Â bar range from 2147 to 2840Â barrers and the permselectivities of CO2/N2 and CO2/CH4 in them approach to 178-265 and 98-221, respectively. However, when the anions of dicarboxylate-based ILs are half deprotonated, they are efficient solvents for the selective separation of SO2. Triethylbutylammonium dimalonate ([N2224][dimalonate]) could facilitate the permeation of SO2 with a permeability of 7208Â barrers under the transmembrane pressure difference of 0.05Â bar, and the permselectivities of SO2/N2, SO2/CH4 and SO2/CO2 are 585, 271 and 18, respectively. The mechanism of facilitated separation is explained successfully from the reversible reactions of CO2 and SO2 with different forms of dicarboxylate-based ILs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 471, 1 December 2014, Pages 227-236
Journal: Journal of Membrane Science - Volume 471, 1 December 2014, Pages 227-236
نویسندگان
Kuan Huang, Xiao-Min Zhang, Ya-Xin Li, You-Ting Wu, Xing-Bang Hu,