کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
702352 1460810 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Initial stage of carbon nanotube formation process by surface decomposition of SiC: STM and NEXAFS study
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی برق و الکترونیک
پیش نمایش صفحه اول مقاله
Initial stage of carbon nanotube formation process by surface decomposition of SiC: STM and NEXAFS study
چکیده انگلیسی

Formation process of carbon nanocaps, which are formed at the beginning of carbon nanotube (CNT) growth by surface decomposition of SiC, was investigated by scanning tunneling microscopy (STM) and in situ near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. As Si atoms were desorbed, carbon nanoparticles 1–2 nm in diameter were accumulated on SiC(000-1) surfaces. At around 1200 °C, these were coalesced and crystallized to carbon nanocaps. In addition, just before the crystallization, majority of C–C bonds were directed nearly parallel to the surface. Based on these experimental results, we proposed a model for carbon nanocap formation, which plays an important role to determine the CNTs.


► We propose a model for carbon nanocap formation process by surface decomposition of SiC.
► We carried out STM observation.
► Amorphous carbon nanoparticles were coalesced to carbon nanocaps.
► We carried out in situ NEXAFS measurements.
► C–C bonds were directed to nearly parallel to the SiC surface at the beginning of crystallization.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Diamond and Related Materials - Volume 20, Issue 10, November 2011, Pages 1325–1328
نویسندگان
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