کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7043521 | 1456913 | 2018 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reactive separation of protocatechuic acid using Tri-n-octyl amine and Di-(2-ethylhexyl) phosphoric acid in Methyl isobutyl ketone
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reactive separation of protocatechuic acid using Tri-n-octyl amine and Di-(2-ethylhexyl) phosphoric acid in Methyl isobutyl ketone Reactive separation of protocatechuic acid using Tri-n-octyl amine and Di-(2-ethylhexyl) phosphoric acid in Methyl isobutyl ketone](/preview/png/7043521.png)
چکیده انگلیسی
Protocatechuic acid is used extensively in pharmacological and related industries which can also be obtained by fermentation. Reactive separation by means of reactive extractant is a favourable alternative to recover carboxylic acids from the aqueous dilute streams and the fermentation broth. In this paper, the reactive separation of protocatechuic acid were performed by D2EHPA (Di-(2-ethylhexyl) phosphoric acid) and TOA (tri-n-octyl amine) dissolved in MIBK (Methyl isobutyl ketone) at 298â¯K. Distribution coefficients, degree of extraction, complexation constants and loading ratio were estimated. The equilibrium for protocatechuic acid-extractant-diluent system was represented using Langmuir model, mass action law and relative basicity model. Results obtained from model were found to be close to experimental data. TOA was found more effective than D2EHPA for the recovery of protocatechuic acid having 5.39 as maximum distribution coefficient and 84.36% efficiency at 0.01â¯molâ¯Lâ1 and 1.1437â¯molâ¯Lâ1 concentration of protocatechuic acid and TOA respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 207, 22 December 2018, Pages 99-107
Journal: Separation and Purification Technology - Volume 207, 22 December 2018, Pages 99-107
نویسندگان
Fiona Mary Antony, Kailas L. Wasewar,