کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7107117 | 1460525 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, photophysical and photochemical studies of benzophenone based novel monomeric and polymeric photoinitiators
ترجمه فارسی عنوان
سنتز، مطالعات فتوفیزیک و فتوشیمیایی عکسهای اولیهای مونومرز و پلیمری مبتنی بر بنزوفنون
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کلمات کلیدی
عکسبرداری، بنزوفنون، آغازگرهای پلیمری، متاکریلات، پلیمریزاسیون رادیکال، سنتز،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
چکیده انگلیسی
Four novel benzophenone-containing photoinitiators (monomers PI-1 and PI-2 and their polymers PPI-1 and PPI-2) were prepared from alkyl α-hydroxymethacrylates. PI-1 was synthesized from reaction of tert-butyl α-bromomethacrylate and 4-hydroxybenzophenone followed by cleavage of tert-butyl groups using trifluoroacetic acid. PI-2 was synthesized from reaction of ethyl α-bromomethacrylate and 3-benzoylbenzoic acid. Thermal polymerization of PI-1 and PI-2 was performed using 2,2â²-azobis(isobutyronitrile). PI-1 and PPI-1 show UV absorption (289 and 294 nm) which are red-shifted compared to benzophenone (252 nm), PI-2 (255 nm) and PPI-2 (252 nm). All of the photoinitiators give phosphorescence emissions from their n-Ï* states. The photopolymerizations of triethylene glycol dimethacrylate, 2-hydroxyethyl methacrylate and hexanediol diacrylate initiated by PI-1, PI-2, PPI-1, PPI-2 and benzophenone were studied by photo-differential scanning calorimeter using N,N-dimethyl-p-toluidine as coinitiator. Polymeric photoinitiators were found to have higher efficiencies than benzophenone and monomeric ones. Photopolymerization results are also compared to that of an alkyl α-hydroxymethacrylate-based photoinitiator previously reported by us; and the influence of monomer structure on polymerization efficiency is discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Organic Coatings - Volume 78, January 2015, Pages 200-207
Journal: Progress in Organic Coatings - Volume 78, January 2015, Pages 200-207
نویسندگان
Demet Karaca Balta, Ãzlem Karahan, Duygu Avci, Nergis Arsu,