کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7211926 1469338 2018 26 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Morphological, rheological and electrical properties of composites filled with carbon nanotubes functionalized with 1-pyrenebutyric acid
ترجمه فارسی عنوان
خواص مورفولوژیکی، رئولوژیکی و الکتریکی کامپوزیت ها پر شده با نانولوله های کربنی با 1-پیرونی بوتیریک اسید
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی (عمومی)
چکیده انگلیسی
Non-covalent functionalization of Multi Wall Carbon Nanotubes (MWCNTs) could provide a solution for preserving their electronic structure facilitating the nanocomposite process preparation. Functionalization of MWCNTs by π-stacking interaction between nanofiller and a pyrene derivative has been explored. The rheological properties of filled epoxy resins highlight very interesting benefits from this kind of functionalization. Besides its peculiar capability for preventing agglomeration in the nanofiller dispersion step, it also efficiently contributes to a decrease in the viscosity of the nanocomposites; hence contrasting one of the most relevant drawback related to the manufacturing processes of the nanocomposites at MWCNTs loading rates beyond the Electrical Percolation Threshold (EPT). Because no damage of MWCNTs occurs, sp2 hybridization of carbon atoms is preserved together with the π-electron delocalization typical of polynuclear aromatic rings. Consequently, no deterioration in the electrical properties are detected; the measured EPT values are typical of nanocomposites containing embedded unfunctionalized MWCNTs (lower than 0.28 wt%), whereas for the electrical conductivity beyond the EPT, an enhancement is observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Part B: Engineering - Volume 147, 15 August 2018, Pages 12-21
نویسندگان
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